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TO THY OWN SELF BE TRUE
自
You will see so many instances of the primary meaning / reading of this kanji, that you may forget all about an irregular (but important) on reading. Below are some examples of words based on the “self”-related JI / mizukara readings, as well as some words based on the SHI reading. The SHI reading is the first component of the Japanese word for nature, shizen 自然.
JI / mizukara- ("self") based words:
自分（じぶん）self
自己紹介（じこしょうかい） self-introduction
自制（じせい） self-restraint
自殺（じさつ） suicide
SHI-based words
自然科学（しぜんかがく） the natural sciences
不自然（ふしぜん）unnatural
超自然 （ちょうしぜん）supernatural
大自然（だいしぜん）Mother Nature